Nova新书Organometallic Chemistry - Research Perspect ...？ Organometallic Chemistry Research Perspectives By: Richard P. Irwin(Editor) ISBN-10: 160021780X ISBN-13: 9781600217807 Publisher: Nova Science Publishers - 2008-03-30 Hardcover | 1 Edition | 309 Pages | List Price: $129.00 (USD) | Sales Rank: 4660711 Product Dimensions: 10.39 x 7.01 x 1.02 inches Product Description Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species.In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium. Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers. This book presents leading-edge new research in the field. CONTENTS Preface vii Chapter 1 Polyhedral Boron Hydrides in Use: Current Status and Perspectives 1 Chapter 2 Hydrosilylation of CH2=CH- Groups Immobilized on the Interlayer Surface of an Ion-Exchangeable Layered Perovskite with Hydorochlorosilanes and Oligosiloxanes 61 Chapter 3 Use of Electrochemistry and Palladium Catalysts for an Efficient Synthesis of Carbonyl Compounds 83 Chapter 4 Mixed Transition Metal Acetylides with Different Metals Connected by Carbon-Rich Bridging Units: On the Way to Heteromultimetallic Organometallics 99 Chapter 5 Recent Advances in Organometallic Materials Derived from Ferrocenylacetylide 165 Chapter 6 The Bio-Organometallic Chemistry of [2Fe2S] Models Related to Iron Hydrogenase Active Site 197 Chapter 7 Recent Advances in Organotin(IV) Complexes Containing Sn-S Bonds 221 Chapter 8 Organometallic Complexes of Rhodium(I), Iridium(I) and Ruthenium(II) Containing Hemilabile Functionalized Phosphine-Chalcogen Donor Ligands : Synthesis, Reactivities and Applications 249 Chapter 9 Electronic Properties of Transition Metal Carbene and Silylene Complexes - A Quantum Chemical Study at Selected Model Complexes 289 Index 299 [ ]查看更多0个回答 . 4人已关注
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