求助一篇文章：Solubility of chlorine in tetrachlorid ...？ 具体内容如下！ Solubility of chlorine in tetrachlorides. Martynov, Yu. M.; Davidovskaya-Chemelinskaya, I. V.; Borodulina, E. K. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation) (1966), 39(12), 2650-5. CODEN: ZPKHAB ISSN: 0044-4618. Journal written in Russian. CAN 66:59361 AN 1967:59361 CAPLUS Abstract The systems Cl-CCl4, Cl-SiCl4, Cl-TiCl4, Cl-SnCl4 were examd. in an absorption vessel fitted with a magnetic stirrer by introducing the solvent (15-25 g.), cooling the vessel to -70°, evacuating the system to 3-5 torr, and then heating it to a given temp. A measured vol. of Cl was introduced, and after the establishment of equil. the pressure was read on a Hg manometer. The dependence between the partial pressure of Cl and its concn. in the soln. at const. temp. (T) is linear in all cases. The relations between the logarithm of the Henry coeff. (H) and the abs. temp. are: for Cl-CCl4 log H = -879/T + 3.74; for Cl-SiCl4 log H = -924/T + 3.93; for Cl-TiCl4 log H = -941/T + 4.0; for Cl-SnCl4 log H = -996/T + 4.16. The heats of dissoln. of Cl do not depend on temp. within the temp. range studied. The behavior of the systems considered is distinguished by a systematic decrease of the heat of dissoln., i.e. by a regular change in the value of interaction between the components of the solns. The relative error of the measurements did not exceed ±5%. The molar differential heats of dissoln. of Cl are linearly related to the logarithm of the ordinal no. of the central element of the mol. of the solvent. 15 references. 在此先谢谢各位仁兄了！查看更多0个回答 . 3人已关注
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