反应器中出现如下的错误,求助? 邻硝基苯胺 的重氮化反应:C6H6N3O2+2HCL+NaNO2-> C6H4N3O2CL+NaCL+2H2O,采用什么方程?选用nrtl,出现了如下的提示,请大师帮忙!!不胜感激 -> rocessing input specifications * WARNING IN PHYSICAL PROPERTY SYSTEM THE FOLLOWING CONVENTIONAL COMPONENTS WERE NOT IN A DATA BANK. CHECK DATA BANK NAMES FOR SPELLING. CID DATA BANK NAME C6H4N3O2 C6H4N3O2CL STRUCTURE FOR COMPONENT O-NIT-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT HYDRO-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-02 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT WATER HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT C6H4N3O2 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC REACTION NUMBER "1" DOES NOT SATISFY MASS BALANCE. THE ABSOLUTE ERROR IS 0.10520E-01 CHECK STOICHIOMETRY/MOLECULAR WEIGHTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC PHYSICAL PROPERTY PARAMETER DHFORM OR DHAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: C6H4N3O2 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. Flowsheet Analysis : COMPUTATION ORDER FOR THE FLOWSHEET: B1 ->Calculations begin ... *** SEVERE ERROR IN PHYSICAL PROPERTY SYSTEM SPECIFIC VOLUME MODEL VL2RKT HAS MISSING PARAMETERS: PC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 VCRKT AND ITS DEFAULT VC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 RKTZRA AND ITS DEFAULT ZC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 ****PROPERTY PARAMETER ERROR ERRORS ENCOUNTERED IN CALCULATION OF LIQUID MIXTURE PROPS USING OPTION SET NRTL FOR SMX,VMX ! Calculations stopped because of missing property parameters -> rocessing input specifications ... * WARNING IN PHYSICAL PROPERTY SYSTEM THE FOLLOWING CONVENTIONAL COMPONENTS WERE NOT IN A DATA BANK. CHECK DATA BANK NAMES FOR SPELLING. CID DATA BANK NAME C6H4N3O2 C6H4N3O2CL STRUCTURE FOR COMPONENT O-NIT-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT HYDRO-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-02 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT WATER HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT C6H4N3O2 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC REACTION NUMBER "1" DOES NOT SATISFY MASS BALANCE. THE ABSOLUTE ERROR IS 0.10520E-01 CHECK STOICHIOMETRY/MOLECULAR WEIGHTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC PHYSICAL PROPERTY PARAMETER DHFORM OR DHAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: C6H4N3O2 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. Flowsheet Analysis : COMPUTATION ORDER FOR THE FLOWSHEET: B1 ->Calculations begin ... *** SEVERE ERROR IN PHYSICAL PROPERTY SYSTEM SPECIFIC VOLUME MODEL VL2RKT HAS MISSING PARAMETERS: PC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 VCRKT AND ITS DEFAULT VC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 RKTZRA AND ITS DEFAULT ZC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 ****PROPERTY PARAMETER ERROR ERRORS ENCOUNTERED IN CALCULATION OF LIQUID MIXTURE PROPS USING OPTION SET NRTL FOR SMX,VMX ! Calculations stopped because of missing property parameters -> rocessing input specifications ... * WARNING IN PHYSICAL PROPERTY SYSTEM THE FOLLOWING CONVENTIONAL COMPONENTS WERE NOT IN A DATA BANK. CHECK DATA BANK NAMES FOR SPELLING. CID DATA BANK NAME C6H4N3O2 C6H4N3O2CL STRUCTURE FOR COMPONENT O-NIT-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT HYDRO-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-01 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT SODIU-02 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT WATER HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. STRUCTURE FOR COMPONENT C6H4N3O2 HAS NOT BEEN DEFINED. PCES CANNOT USE GROUP-CONTRIBUTION METHODS TO ESTIMATE MISSING PROPERTIES USE THE STRUCTURES PARAGRAPH TO DEFINE STRUCTURES OF THIS COMPONENT. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC REACTION NUMBER "1" DOES NOT SATISFY MASS BALANCE. THE ABSOLUTE ERROR IS 0.10520E-01 CHECK STOICHIOMETRY/MOLECULAR WEIGHTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: B1 MODEL NAME: RSTOIC PHYSICAL PROPERTY PARAMETER DHFORM OR DHAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: C6H4N3O2 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. Flowsheet Analysis : COMPUTATION ORDER FOR THE FLOWSHEET: B1 ->Calculations begin ... *** SEVERE ERROR IN PHYSICAL PROPERTY SYSTEM SPECIFIC VOLUME MODEL VL2RKT HAS MISSING PARAMETERS: PC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 VCRKT AND ITS DEFAULT VC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 RKTZRA AND ITS DEFAULT ZC (DATA SET 1) MISSING FOR COMPONENT SODIU-01 ****PROPERTY PARAMETER ERROR ERRORS ENCOUNTERED IN CALCULATION OF LIQUID MIXTURE PROPS USING OPTION SET NRTL FOR SMX,VMX ! Calculations stopped because of missing property parameters 查看更多0个回答 . 1人已关注