求助有关极化曲线拟合公式成立条件问题？朋友审稿意见回来，其中一条审稿意见很棘手，我用非线性拟合极化曲线，所用的公式如附件Eq (2), 审稿人意思说我的这个极化曲线拟合公式只适合在电荷转移控制下情况。而不符合在有传质控制下极化曲线，想请问大神们，怎么回答这个意见？朋友必将重金感谢。以下是审稿人意见：Eqs. (2)-(4) 。These equations are established when a charge transfer is a rate-determining step (rds). In the employed corrosion system of Zn, mass transport steps will affect both anodic and cathodic reactions. In addition, it is clear from EIS data that adsorption process is involved in the corrosion reaction. I think it is difficult to apply the pre-Tafel region analysis to this complicated corrosion system. Actually, the values of the Tafel slopes in Table 2 are not reasonable and are very scattered. The change of Tafel slope means changes of the reaction mechanism (rds). I doubt the mechanisms (rds) of anodic and cathodic reactions change by RH (75, 85 and 97%RH) and change with exposure time, although the reaction rates change by RH and exposure time.附件.gif查看更多3个回答 . 7人已关注
快被审稿人疯了！大家帮忙看看这条意见到底是什么意思！万分捉急啊！？小弟不才，将近研三才投出去论文。杂志是JEC，结果审了一个月，邀请了四位审稿人，编辑给了大修。其中有个审稿人意见极其刻薄，很多问题难以回答。其中有这个问题，我自己看了很多遍，确实不懂说的什么意思。问老师之后，也没办法明白含义。请大家帮忙看看~ 万分感谢！ 8.- Sensitivity of the electrochemical DNA biosensor Why in the calibration curve not considered as analytical signal the difference in current between ssDNA and dsDNA, as in other works in literature.??The difference in current could help any possible discrimination for other DNA sequences. What happen with the current value between DNA species and GC electrode. They need to perform such control experiment. 这个检测限的标准曲线拟合出来之后，为什么要弄什么单链DNA和双链DNA的电信号？实在是搞不懂。 还说在其他文献中都有，可是我看了很多做检测类的文献，都是把目标DNA检测后，拟合检测限，然后就得出定量检测的结论。没有见到过说什么单链DNA和双链DNA的电信号区别。。。。 中秋佳节将至，论文修改屡屡上火。而且运气这么差的遇到了4个审稿人，这日子简直没发过了。。。恳请各位同学和老师帮忙看看这条意见到底是什么意思，万分感谢！查看更多5个回答 . 12人已关注
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