纯水的化学势 自由能？ 对于纯水，在给定温度压力下(达到热力学平衡)，平均缔合程度是确定不变的，要让缔合程度不同，只能是改变温度和压力。温度越低，压力越大（温度的影响大得多，压力的影响很小，通常可以忽略），缔合程度越高。dgm ... 英文原著 我应该不会理解错吧if the self-associated network is more complete than somearbitrary reference state, then there must be relatively fewerunmatched lewis acid–base pairings than in this referencestate. conversely, in less-associated water, the network isrelatively incomplete and there are more unmatched lewisacid–base pairings than in the reference state. these unmatchedpairings in less associated water are readily available to participatein other chemical reactions, such as dissolving a solutemolecule or hydrating a water-contacting surface. therefore,it can be generally concluded that less-associated water isa stronger solvent than more-associated water because ithas a greater potential to engage in reactions other thanself-association. in chemical terminology, less self-associatedwater has a greater chemical potential than more selfassociatedwater， 查看更多
第1天
关注盖德视界
添加小助手
