35%的过氧乙酸工业上能用吗? 采用原位生成的方法是比较安全，可以用乙酸作溶剂，加入底物后，滴加双氧水，理论当量是1，需要优化调整下。 楼主说的安评应是企业内部的安全评价体系吧。对于一个危险的反应该做哪些研究，可以看下我写的安全源于设计。安全不是口号，也不是评价下有无危险，是一个体系，是否舍得投入呢。对于非常危险的反应，至少请科研院所做下量热反应，反应的放热量，能达到的最大温度，分解温度，有无二次分解的可能？ poison by ingestion. moderately toxic by inhalation and skin contact. a corrosive eye, skin, and mucous membrane irritant. questionable carcinogen with experimental tumorigenic data by skin contact. flammable liquid. severe explosion hazard when exposed to heat or by spontaneous chemical reaction. explodes violently at 110°c. a powerful oxidizing agent. explosive reaction with acetic anhydride, 5-p-chlorophenyl-2,2- dimethyl-3-hexanone. violent reaction with ether solvents (e.g., tetrahydrofuran, diethyl ether), metal chloride solutions (e.g., calcium chloride, potassium chloride, sodium chloride), olefins, organic matter. dangerous; keep away from combustible materials. when heated to decomposition it emits acrid smoke and irritating fumes. to fight fire, use water, foam, co2. 查看更多
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