这样做异辛酸，行否? 可以利用双氧水的复合物，例如：hydrogen peroxideammonium heptamolybdate h2o2-(nh4)6mo7o24.4h2o， oxidation of secondary alcohols to ketones with hydrogen peroxide-heptamolybdate is accelerated by the addition of potassium carbonate.2,3 the oxidation of a secondary alcohol chemoselectively occurs in the presence of a primary alcohol (eq 4).2-5 steric factors play an important role in these oxidations: the more hindered alcohol is oxidized more rapidly.2 this steric effect has been exploited for selective oxidations of steroids (eq 5).2,3 primary alcohols are oxidized to carboxylic acids at higher temperatures but the major products are the self-condensed esters. aldehydes are oxidized to carboxylic acids by this reagent (eq 6).2 trost, b. m.; masuyama, y. isr. j. chem. 1984, 24, 134. trost, b. m.; masuyama, y. tl 1984, 25, 173. 个人认为条件太强易形成酯，可以考虑先醛，再氧化成酸查看更多
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