这样做异辛酸,行否? 以前见过把醇和酚氧化成醛和醌酮的文献,你可能看过,供参考 the system h2o2/rucl3.3h2o/phase-transfer catalyst (didecyldimethylammonium bromide) oxidizes a variety of alcohols selectively; the requirement of ruthenium is very low; ratio of substrate:rucl3 = 625:1 by this method, p-methylbenzyl alcohol was oxidized to p-methylbenzaldehyde in 100% yield. vicinal diols are oxidized to a-hydroxy ketones by 35% h2o2 in the presence of peroxotungstophosphate barak, g.; dakka, j.; sasson, y. joc 1988, 53, 3553. sakata, y.; ishii, y. joc 1991, 56, 6233. minisci, f.; citterio, a.; vismara, e.; fontana, f.; bernardinis, s. d. joc 1989, 54, 728.查看更多