aspen 模拟带有固体的化学反应? 求大神指教,我想用吉布斯 反应器 模拟一个含有cas( 硫化钙 )和caso4( 硫酸钙 ) 的反应,可是调试有这些问题,到底是怎么回事呢?谁能帮帮我 INFORMATION BINARY PARAMETERS RKSKIJ (DATA SET 1) FOR MODEL ESRKSTD ARE RETRIEVED FROM SDF TABLE. TABLE NAME = ESRKSTD * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: OXD MODEL NAME: RGIBBS WHEN "TRUE-COMPS=YES" IS SPECIFIED WITH A CHEMISTRY PARAGRAPH, MASS BALANCE OR CONVERGENCE PROBLEMS MAY ARISE IF COMPONENTS PARTICIPATE IN BOTH CHEMISTRY AND REACTIONS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: OXD MODEL NAME: RGIBBS PHYSICAL PROPERTY PARAMETER DHFORM OR DHAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: CASO4 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: OXD MODEL NAME: RGIBBS PHYSICAL PROPERTY PARAMETER DGFORM OR DGAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: CASO4 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: RED MODEL NAME: RGIBBS WHEN "TRUE-COMPS=YES" IS SPECIFIED WITH A CHEMISTRY PARAGRAPH, MASS BALANCE OR CONVERGENCE PROBLEMS MAY ARISE IF COMPONENTS PARTICIPATE IN BOTH CHEMISTRY AND REACTIONS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: RED MODEL NAME: RGIBBS PHYSICAL PROPERTY PARAMETER DHFORM OR DHAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: CASO4 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. * WARNING WHILE CHECKING INPUT SPECIFICATIONS BLOCK NAME: RED MODEL NAME: RGIBBS PHYSICAL PROPERTY PARAMETER DGFORM OR DGAQFM IS MISSING FOR THE FOLLOWING COMPONENTS: CASO4 ABSENCE OF THIS PARAMETER MAY RESULT IN INCORRECT ENTHALPY RESULTS. Flowsheet Analysis : COMPUTATION ORDER FOR THE FLOWSHEET: COM OXD MOXD PRH RED MRED GSH ->Calculations begin ... *** SEVERE ERROR IN PHYSICAL PROPERTY SYSTEM PARAMETERS OF RKS EQUATION OF STATE ARE MISSING. TC IN DATA SET 1 IS MISSING FOR CAS; A NOMINAL VALUE OF 507.40 K HAS BEEN ASSUMED. PC IN DATA SET 1 IS MISSING FOR CAS; A NOMINAL VALUE OF 0.29688E+07 PA HAS BEEN ASSUMED. OMEGA IN DATA SET 1 IS MISSING FOR CAS; A NOMINAL VALUE OF 0.29600 HAS BEEN ASSUMED. ZRA IN DATA SET 1 IS MISSING FOR CAS; A NOMINAL VALUE OF 0.31470 HAS BEEN ASSUMED. ****PROPERTY PARAMETER ERROR ERRORS ENCOUNTERED IN CALCULATION OF VAPOR MIXTURE PROPS USING OPTION SET RK-SOAVE FOR PHIMX ! Calculations stopped because of missing property parameters 查看更多7个回答 . 4人已关注