求一片参考文献，百度搜不到？求一片文章 Hart, A. C.; Shaw, P. J. Targeting Necroptosis for Therapeutic Intervention in Inflammatory Diseases. In Medicinal Chemistry Reviews; Desai, M. J., Ed.; ACS: Washington, DC, 2016; Vol. 51, pp 101−114.查看更多3个回答 . 9人已关注
不对称拆分的s-factors是什么意思？怎么计算得到的?如题，求助。 To gain insight into the reaction, we obtained sets of reaction kinetics by 1H-NMR (Figure 2). The kinetics for both enantiomers of 1a with one equivalent of diazoester 2a were separately measured. Complete conversion for the fast reacting Renantiomer (red line) is reached at 6.5 hours. The conversion of the slow reacting S-enantiomer (blue line) was very sluggish. After 10 hours, more than 90 % of (S)-1a remained. This roughly equals to a rate difference of 20, well matching to the observed resolution selectivities. The reaction of rac-1a (black line) with a full equivalent of 2a shows a significant decrease in reaction rate after the 6.5 hour mark. This 50 % substrate conversion corresponds to a complete consumption of the matching enantiomer. ]~LEYX`47QJIZXJQ@C5ZIGL.png A`QG)]M[OCI)FYA{76H}{PK.png查看更多2个回答 . 15人已关注
文章中关于色谱毛细管柱的描述？之前投了一篇文章，对 毛细管柱 的描述如下：A carbon-2000 capillary column purchased from LanZhou Institute of Chemical Physics in China was equipped, operating at 60°C for 1.5 min, followed by a 40°C∙min-1 ramp to 150°C and held for 5 min. 前几天收到审稿意见，有一条意见是这样的：how did you equip the column？不太理解审稿人是什么意思，特此求助，谢谢各位大佬！查看更多3个回答 . 14人已关注
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