为什么测光电流时在打开和关闭灯源的瞬间光电流会突然增大呢?这个应该是由载流子发生复合所致:以alpha-Fe2O3为例,瞬间开始光照时光电流会由暗电流值激增到一个较高值而后锐减至一稳态值;瞬间停止光照时,光电流会由稳态值急降至一比暗电流还低的值,而后又回升至暗电流值;文献称呼这个叫暂态光电流“transient photocurrent”,对其解释为:The instantaneous current when the light is switched on is a measure of the flux of holes into the surface. The subsequent decay towards the steady state current results from the capture of build-up holes in surface states inducing an electron fluxassociated with recombination. The cathodic current overshoot observed when the light is switched off is due to the continuing flux of electrons into the surface as holes remaining in the surface states recombine.文献出处:Cummings, C. Y.; Marken, F.; Peter, L. M.; Tahir, A. A.; Wijayantha, K. G. U. Chemical Communications 2012, 48, (14), 2027-2029,查看更多