画出Scharifker-Hills三维成核模型的? 建议先阅读较早的关于公式推导的文献(见文末),这里仅将我个人理解简单陈述(见附件),仅做交流,剩下的还得靠你自己理解文献。 前提:你用正确的方法测出类似下图的i-t曲线1(暂态曲线),注意:并不是所有的都长这样,有的会有诱导区(如右图2-3)。 拟合有两种方式:与两个极端对比和非线性拟合 1.? ? ? ? scharifker, b.; hills, g., theoretical and experimental studies of multiple nucleation. electrochim. acta 1983, 28 (7), 879-889. 2.? ? ? ? zhang, j.; an, m.; chen, q.; liu, a.; jiang, x.; ji, s.; lian, y.; wen, x., electrochemical study of the diffusion and nucleation of gallium(iii) in [bmim][tfo] ionic liquid. electrochim acta 2016, 190, 1066-1077. 3.? ? ? ? rigano, p. m.; mayer, c.; chierchie, t., electrochemical nucleation and growth of copper on polycrystalline palladium. j. electroanal. chem. 1988, 248 (1), 219-228. 4.? ? ? ? tsakova, v.; milchev, a., comparative studies of electrochemical phase formation by amperometric and microscopic methods: part i. nucleation kinetics in dilute solutions of mercury nitrate. journal of electroanalytical chemistry and interfacial electrochemistry 1987, 235 (1–2), 237-247, 查看更多