急求甲烷重整活化能数据!?刚刚在ChemSUSChem上看到一篇最新的文献,可惜我们单位不能下载。哪位可以下载的话,请传一份给我!先谢谢!zyhou@zju.edu.cn这篇文章中提及甲烷及二氧化碳转化的活化能: The experimental data were analyzed based on the proposed reaction mechanism using the Langmuir–Hinshelwood kinetic model. The activation energies for methane and carbon dioxide consumption were estimated at 52.9 and 48.1?kJ?mol?1, respectively. The lower value of CO2 activation energy compared to the activation energy of CH4 indicated a higher reaction rate of CO2, which owes to the strong basicity of nanocrystalline support, MgO–ZrO2.文章出处:Utilization of Greenhouse Gases through Dry Reforming: Screening of Nickel-Based Bimetallic Catalysts and Kinetic StudiesMun-Sing Fan, Dr. Ahmad Zuhairi Abdullah, Prof.?Dr. Subhash BhatiaArticle first published online: 6 OCT 2011DOI: 10.1002/cssc.201100113,查看更多