1_1_1_ ，2-四氟乙烷英文介绍？ Material Safety Data Sheet Jincool ® HFC-134a Part 1. Chemical Product and Company Identification Product Name: Jincool® HFC-134a Other/Generic Names: HFC-134a,R134a Production Use: Refrigerant, Foam blowing agent, Aerosol Hazard Class: 2.2, Non-flammable gas Chemical attribute: Halohydrocarbon Manufacturer: Sinochem Environmental Protection Chemicals (Taicang) Co., Ltd Add.: No.18, Binjiang Road, Shihua Park, Taicang, Jiangsu, PR of China Call for more information: +86-512-53713100 Call in case of emergency: +86-512-53713126 F F—C—C—H F F H Part 2. Composition / Information on Ingredients Ingredient Name: 1,1,1,2-Tetrafluoroethane Molecular formula: C2H2F4 Structural formula: Relative molecular mass: 102.00 CAS No.: 811-97-2 Purity: Standard≥99.5% Excellent ≥99.9% Appearance: Clear, colorless liquid and vapor, no turbidity or foul smell Part 3. Hazards Identification Potential Health Hazards Skin: Irritation would result from a defatting action on tissue. Liquid contact could cause frostbite. Eyes: Liquid contact can cause severe irritation and frostbite. Mist may irritate. Inhalation: Jincool® 134a is low in acute toxicity in animals. When oxygen levels in air are reduced to 12-14% by displacement, symptoms of asphyxiation, loss of coordination, increased pulse rate and deeper respiration will occur. At high levels, cardiac arrhythmia may occur. Ingestion: Ingestion is unlikely because of the low boiling point of the material. Should it occur, discomfort in the gastrointestinal tract from rapid evaporation of the material and consequent evolution of gas would result. Some effects of inhalation and skin exposure would be expected. Delayed Effects: None known Part 4. First Aid Measures Skin: Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Get medical attention if symptoms persist. Eyes: Immediately flush eyes with large amounts of water for at least 15 minutes (in case of frostbite water should be lukewarm, not hot) lifting eyelids occasionally to facilitate irrigation. Get medical attention if symptoms persist. Inhalation: Immediately remove to fresh air. If breathing has stopped, give artificial respiration. Use oxygen as required, provided a qualified operator is available. Get medical attention. Do not give epinephrine (adrenaline). Ingestion: Ingestion is unlikely because of the physical properties and is not expected to be hazardous. Do not induce vomiting unless instructed to do so by a physician. Advice to Physician: Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of symptoms and the clinical conditions. Part 5. Fire Fighting Measures Flammable Properties Flash Point: Gas, not applicable Flash Point Method: Not applicable Autoignition Temperature: >750°C Upper Flame Limit (volume% in air): None* Lower Flame Limit (volume% in air): None* Flame Propagation Rate (solids): Not applicable Extinguishing Media: Use any standard agent – choose the one most appropriate for type of surrounding fire (material itself is not flammable) Unusual Fire and Explosion Hazards: Jincool® 134a is not flammable at ambient temperatures and atmospheric pressure. However, this material will become combustible when mixed with air under pressure and exposed to strong ignition sources. Contact with certain reactive metals may result in formation of explosive or exothermic reactions under specific conditions (e.g. very high temperatures and/or appropriate pressures). Special Fire Fighting Precautions/Instructions: Firefighters should wear self-contained breathing apparatus for protection against possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool. Part 6. Accidental Release Measures In Case of Spill or other Release: Always wear recommended personal protective equipment. Evacuate unprotected personnel. Protected personnel should remove ignition sources and shut off leak, if without risk, and provide ventilation. Unprotected personnel should not return until air has been tested and determined safe, including lowlying areas. Spills and releases may have to be reported to local authorities. Part 7. Handling and Storage Normal Handling: Always wear recommended personal protective equipment. Avoid breathing vapors and liquid contact with eyes, skin or clothing. Do not puncture or drop cylinders, expose them to open flame or excessive heat. Use authorized cylinders only. Follow standard safety precautions for handling and use of compressed gas cylinders. Jincool® 134a should not be mixed with air above atmospheric pressure for leak testing or any other purpose. Storage Recommendations: Store in a cool, well-ventilated area of low fire risk and out of direct sunlight. Protect cylinder and its fittings from physical damage. Storage in subsurface locations should be avoided. Close valve tightly after use and when empty. Part 8. Exposure Controls / Personal Protection Engineering Controls: Provide local ventilation at filling zones and areas where leakage is probable. Mechanical (general) ventilation may be adequate for other operating and storage areas. Personal Protective Equipment Skin Protection: Skin contact with refrigerant may cause frostbite. General work clothing and gloves (leather) should provide adequate protection. If prolonged contact with the liquid or gas is anticipated, insulated gloves constructed of PVA, neoprene or butyl rubber should be used. Any contaminated clothing should be promptly removed and washed before reuse. Eye Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear chemical safety goggles. Respiratory Protection: None generally required for adequately ventilated work situations. For accidental release or non-ventilated situations, or release into confined space, where the concentration may be above the PEL of 1,000 ppm, use a self-contained breathing apparatus or supplied air respirator. For escape: use the former or a gas mask with organic vapor canister. Additional Recommentations: Where contact with liquid is likely, such as in a spill or leak, impervious boots and clothing should be worn. High doselevel warning signs are recommended for areas of principle exposure. Provide eyewash stations and quick-drench shower facilities at convenient locations. For tank cleaning operations, see OSHA regulations, 29 CFR 1910.132 and 29 CFR 1910.133 Exposure Guidelines: INGREDIENT NAME ACGIH TLV OSHA PEL OTHER LIMIT 1,1,1,2-Tetrafluoroethane None None *1000 ppm TWA (8hr) * = Workplace Environmental Exposure Level (AIHA). Part 9. Physical and chemical properties PHYSICAL STATE: Gas at ambient temperatures MOLECULAR WEIGHT: 102 CHEMICAL FORMULA: F3CCH2F ODOR: Faint ethereal odor SPECIFIC GRAVITY (water = 1.0): 1.206 SOLUBILITY IN WATER (wt %): 0.15 wt%S pH: Neutral BOILING POINT: -26.2°C (-15.1°F) FREEZING POINT: -92.5°C (-141.9°F) VAPOR PRESSURE: 666.1 Kpa @ 25°C VAPOR DENSITY (air = 1.0): 5.25 FLASH POINT: Not applicable CRITICAL TEMPERATURE: 101.1°C CRITICAL PRESSURE: 4.06 Mpa OCTANOL WATER PARTITION COEFFICIENT: Log Pow = 1.06 Part 10. Stability and Reactivity Normally Stability: The product is stable. Do not mix with oxygen or air above atmospheric pressure. Any source of high temperature, such as lighted cigarettes, flames, hot spots or welding may yield toxic and/or corrosive decomposition products. Incompatibilities: (Under specific conditions: e.g. very high temperatures and/or appropriate pressures) – Freshly abraded aluminum surfaces (may cause strong exothermic reaction). Chemically active metals: potassium, calcium, powdered aluminum, magnesium and zinc. Hazardous Decomposition Products: Halogens, halogen acids and possibly carbonyl halides. Hazardous Polymerization: Will not occur. Part 11. Toxicological Information Immediate (Acute) Effects: LC50 : 4 hr. (rat) - > 500,000 ppm Cardiac Sensitization threshold (dog) 80,000 ppm. Delayed (Subchronic and Chronic) Effects: Not mutagenic in four tests Teratogenic NOEL (rat and rabbit) - 40,000 ppm Subchronic inhalation (rat) NOEL - 50,000 ppm Chronic NOEL - 10,000 ppm OTHER DATA: Metabolism <0.5% as CO2 in tests at 50,000 ppm, late developing benign tumors were found. Part 12. Ecological Information This product can destroy the ozone layer but not substantially. It can also pollute the ground surface water, soil, atmosphere and drinking water. Degradability (BOD): Jincool® 134a is a gas at room temperature; therefore, it is unlikely to remain in water. Part 13. Disposal Considerations Refer to the pertinent state and local laws and regulations before disposal. Part 14. Transportation US DOT PROPER SHIPPING NAME: 1,1,1,2-Tetrafluoroethane US DOT HAZARD CLASS: 2.2 US DOT PACKING GROUP: Not applicable US DOT ID NUMBER: UN3159 For additional information on shipping regulations affecting this material, contact the information number found in Part 1. Part 15. Regulation Information LAWS AND REGULATIONS IN CHINA NAME: Regulations on the Control over Safety of Dangerous Chemicals Regulations on Safe Use of Chemicals at Workplace PRESCIBE: production, storage, transportation, loading and unloading TOXIC SUBSTANCES CONTROL ACT (TSCA) TSCA INVENTORY STATUS: Listed on the TSCA inventory OTHER TSCA ISSUES: None Part 16. Miscellaneous CURRENT ISSUE DATE: February, 2008 PREVIOUS ISSUE DATE: January, 2006 The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Sinochem shall not be held liable for any damage resulting from handling or from contact with the above product. END 查看更多1个回答 . 4人已关注
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