生物质催化要完蛋了，甲烷重整要火？不清楚楼主为什么要故意误导大家？Paul J. Dauenhauer and George W. Huber的文章只是Green Chemistry的专辑的引言，对于生物质的发展呈现的是绝对的正面的意见。大家可以看看附件的文章内容，自己做出评断。第二篇文章与甲烷的转化没有丝毫关系，这里是文章的摘要：A dual template synthesis strategy was employed to achieve one-step design of meso- and microporous MFI nanosheet assemblies with tailored morphology, mesoporosity, and catalytic activity. A molecular template (tetrapropylammonium hydroxide, TPAOH) and a polyquaternary ammonium surfactant ([C22H45–N+(CH3)2–C6H12–N+(CH3)2–C6H13]Br2, C22–6–6) were used as cotemplates in the synthesis with a composition of 30Na2O/1Al2O3/100SiO2/10C22–6–6/xTPAOH/4000H2O/18H2SO4. By tuning the concentration of TPAOH (x) from 0 to 20, the morphology of the as-obtained MFI nanosheet assemblies changed from intertwined, to house-of-cards-like, and to dense packing plates. The N2 isotherms showed the hysteresis loop at the range of P/P0 = 0.45–1.0 increases, reaches a maximum, and then decreases with increasing x values, indicating a systematic tailoring of the mesoporosity with TPAOH concentrations. Under strict kinetic control, the rates and apparent activation energies of the ethanol activation in zeolite nanosheet assemblies were comparable. The catalytic conversion of benzyl alcohol in mesitylene showed that the activity of as-obtained MFI zeolites increases, reaching a maximum, and then decreases with increasing x values. The consistency in the variation of morphology, mesoporosity, and catalytic activity with varying x values in the synthesis indicates TPAOH can be used as a secondary template to tailor the textural and catalytic properties of MFI nanosheet assemblies primarily guided by C22–6–6，查看更多
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