求助，神呐，救救我吧？小弟的一篇文章审稿意见回来了，文章小弟测了电化学，化合物里面有二价铜，在循环伏安曲线上在183MV处只有铜的氧化峰，没有还原峰（不可逆的峰），审稿人的意见是：in 2, the cupper is already at the oxidation number of II, so it is difficult to understand the presence of this wave. That would means, firstly the reduction at the electrode of the Cu(II) to Cu(I) and then the oxidation during the scan. But dispropotionation of Cu(I) can also occurs! Why author find irreversible wave ? Usually, such wave must be observed during the reduction of Cu(II) to Cu(I) follow by the disproportionnation to Cu(0) and Cu(II).初学电化学 测试 ，是在不明白怎么解释，导师又不管，求助各位大侠了，谢谢啊查看更多3个回答 . 2人已关注
Nano letter 上面尖晶石包覆层状富锂的文章？Ultrathin Spinel Membrane-Encapsulated Layered Lithium-Rich Cathode Material for Advanced Li-Ion Batteries Lack of high-performance cathode materials has become a technological bottleneck for the commercial development of advanced Li-ion batteries. We have proposed a biomimetic design and versatile synthesis of ultrathin spinel membrane-encapsulated layered lithium-rich cathode, a modification by nanocoating. The ultrathin spinel membrane is attributed to the superior high reversible capacity (over 290 mAh g?1), outstanding rate capability, and excellent cycling ability of this cathode, and even the stubborn illnesses of the layered lithium-rich cathode, such as voltage decay and thermal instability, are found to be relieved as well. This cathode is feasible to construct high-energy and high-power Li-ion batteries.查看更多0个回答 . 17人已关注
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