主编提了个XPS表征的质疑,不知道怎么解答?I'm very uncomfortable with the contention from XPS that Pd exists in a higher oxidation state than +2. XPS is notorious for initial and final state effects as well as reference peak shifts that make oxidation state assignments confusing. Even if Pd does exist in a higher oxidation state, this does necessarily make it a more stable species.查看更多5个回答 . 28人已关注