cof材料合成求助？这是我查到的文献方法 A solution of 6.6 mg (0.028 mmol) of nickel chloride hexahydrate (NiCl2⋅6H2O) in 5 mL of water and 0.3 mL of concentrated aqueous ammonia (NH4OH, 14 mol⋅L -1) was added to a solution of 10 mg (0.019 mmol) of HATP⋅6HCl in 5 mL of water. This mixture was stirred in an open beaker for 2 hours at 65 °C. The resulting black powder was centrifuged, filtered, and then washed in water under reflux for a total of 36 hours (the water was refreshed 2 times during this washing step, for a total of 3 steps, 12 hours each). Finally, the solid was heated at reflux in neat acetone for another 3 h. The solid was then dried under vacuum at 150 °C. C, H, N, and Cl microelemental analysis for Ni3(C18H12N6)2: Calculated: C: 54.00%; H: 3.02%; N: 20.99%; Cl: 0.00%. Found: C: 53.84%; H: 3.12%; N: 20.83%; Cl: 个人认为既然他没提ph的问题，就不用管它，按照这个量合成就好 PS：这个盐酸盐超级贵查看更多
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